Sunday, December 29, 2019

Film Training Day By Starring Denzel Washington And Ethan...

Starring Denzel Washington and Ethan Hawke, the 2001 film Training Day focuses on the portrayal of two Los Angeles Police Department officers.The story begins with Ethan Hawke as Jake Hoyt, a rookie narcotics detective on his first day of assignment. Jake is in a 24 hour period of field evaluation under the reins of a fellow respected and decorated narcotics officer Alonzo Harris, who is portrayed by Denzel Washington. Jake Hoyt is the ideal â€Å"white knight of justice†, an individual who is morally incorruptible, and a person who seeks to defend what is morally correct and to eliminate injustice through proper practices set under federal and state laws and standards. On the other side is Alonzo Harris, a ruthless, selfish, and corrupt narcotics cop who will do whatever it takes to complete the task, whether it violates the procedures and policies. Through the entirety of the film, the concepts of moral ambiguity in situational ethics towards institutional justice and the et hical dilemma of power and corruption amongst enforcement agencies are throughly stressed, analyzed, and reflected. The film illustrates and advances the implicit message of the misrepresentation of the criminal justice system, deception of the effectiveness of institutional justice, and corruption of crime enforcement agencies through the observation, analysis, and deconstruction of numerous examples in normalization to ideologies, and formal elements as suggested through the duration of the film. InShow MoreRelatedI chose the movie clip entitled â€Å"King Kong†. It’s from the movie â€Å"Training Day† starring Denzel800 Words   |  4 PagesI chose the movie clip entitled â€Å"King Kong†. It’s from the movie â€Å"Training Day† starring Denzel Washington. Training Day is a movie that follows a corrupted detective’s day to day mischief as he schools a rookie cop. Training Day depicts a product of the matchup between screenwriter D avid Ayer, who grew up in South Central Los Angeles, and director Antoine Fuqua, who grew up on the rough side of Pittsburgh. Both Ayer and Fuqua are highly familiar with the highly intensified relationship between police

Saturday, December 21, 2019

Conversion to Electronic Health Records Essay - 1039 Words

What an exciting time to become part of the health care industry! Medical research makes new discoveries to improve the quality of patient care and save lives on a daily basis. Health care reform is gaining momentum, revolutionizing the industry and requiring many administrative changes, such as the creation of the Health Insurance Portability and Accountability Act of 1996 (HIPAA). Rules and standards evolved from this act provide a way to ensure your protected health information remains confidential. In this digital age, it is particularly relevant. The digital evolution impacts many areas. Digital TVs, computers, smart phones and iPods have totally changed the way we do business and enjoy entertainment. In the medical industry, the†¦show more content†¦Electronic retrieval of patient demographics, allergies, current medications, complete medical history, diagnostic and radiologic results, etc. occurs by clicking a few buttons. Electronic patient charts provide quick and e asy access to physicians, hospitals, independent labs, and pharmacies. EHRs allow simultaneous access by independent providers and allow a collaborative effort for health care management of the patient. â€Å"EHRs are the next step in the continued progress of healthcare that can strengthen the relationship between patients and clinicians†. (Electronic Health Records Overview, 2011) A lengthy list of EHR benefits supports the evolution from paper to electronic medical record keeping. One such benefit, the significant reduction of needed storage space. Bulky paper charts require a lot of space and misplaced charts waste time and effort to locate. Since EHR data remains on the computer, medical practices no longer require secure on-site storage, and electronic files eliminate misplacing files. Another benefit to data remaining on the computer rather than a medical chart, electronic records allow immediate access from several locations. EHRs provide emergency room personnel access to allergies and other pertinent information of unconscious patients. The on-call physician accesses patient information from their home computer, rather than driving to the medicalShow MoreRelatedThe Conversion Of An Electronic Health Records System For Children s Hospital Of Wisconsin2579 Words   |  11 PagesIntroduction This document outlines the conversion to an electronic health records system for Children’s Hospital of Wisconsin. It is important to note that the conversion process is only the beginning. The process must be clear and understandable to all members of the organization. Members must be trained extensively and retrained on an ongoing basis. Changes must be made in a well thought out manner and this must be communicated effectively to the members that are affected. The effectivenessRead More Privacy and Security Risks for the Electronic Health Record 1081 Words   |  5 Pagesboth paper and electronic records. With the growing demand for the electronic health record (EHR) system, the transfer from paper to electronic can be risky. For this project we were asked to compare and contrast the security issues between maintenance of paper medical records and the EHR system, also we were asked to discuss what requirements and issues need to be considered when doing a conversion t o an EHR. Inappropriate access is one of the most common ways a patient’s record is at risk. InRead MoreThe Health Records Of Healthcare1021 Words   |  5 PagesThe health record has been around for many years, and it first started with a group of individuals in the 1920’s to realize that documenting health care data provided better quality care. Healthcare providers recognized that they were able to treat patients more accurately with a documented history of the patients. It wasn’t until the 1980’s that healthcare professionals started to venture out into the computerized healthcare technology. In the 90’s technology was making gains and healthcareRead MoreMedical Records And Electronic Records998 Words   |  4 Pagespresented multiple issues concerning converting paper medical record to electronic medical records. The first concerns are the inefficiencies of the paper medical records and the steps needed to convert the current records to digital re cords. A second concern was that the medical staff would have to change their work habits to adjust to using the electronic medical records and the training that would be needed to implement the electronic record software. Another concern would be the various formatsRead MoreComputer Security At The Health Care Sector1653 Words   |  7 PagesSecurity in the Health Care Sector Medical records are a very desirable asset on the black market valuing $50.00 each. This is much higher than other personal information including credit card numbers and social security numbers which are valued at $1.50 and $3.00 respectively (Robonsin). The Health Information Technology for Economic and Clinical Health Act (HITECH) has encouraged the health care industry to embrace information technology by adopting electronic health records and electronic informationRead MoreElectronic Medical Records1152 Words   |  5 PagesElectronic Health Records: Are They Worth the Risk? October 18, 2009 Health care is a hot topic in today’s society- everything from reforming the industry so that people are not denied health coverage to finding ways that patients’ medical records can be accessed electronically for more convenience. Moreover, epidemics such as HIV/AIDS spotlights the issues surrounding public health agencies use of maintenance and storage of electronic health records (EHR). Myers, Frieden, Bherwani,Read MoreNotes On Law Office Management952 Words   |  4 PagesInstructor Trina Mebane Assignment 2-1 number 2 on page 39. I found several articles on electronic signatures on contracts and other legal documents at Findlaw.com. I also found several position papers and tutorials on the ABA site, which I skimmed, but for the purposes of this assignment I read â€Å"Contracts and Electronic Signatures† (http://smallbusiness.findlaw.com/business-operations/contracts-and-electronic-signatures.html, Thomas Reuters, 2014). No author was named in the by-line of this articleRead MoreImplementing Organizational Change Essay1574 Words   |  7 PagesImplementing Organizational Change October 22, 2012 Implementing Organizational Change Health care organizations that choose to convert to an electronic medical record system (EMR) have several advantages; most important it increases patient safety, efficiency, cost-effectiveness and security. Accepting such a transition also presents with its share of challenges like preparing for the required significant time obligation and resources that will make the transition a successful one. LeadershipRead MoreEssay National Ehr Mandate1248 Words   |  5 PagesNational EHR Mandate Heidi Babcock-Marvin Ohio University National EHR Mandate An electronic health record (EHR) defines as the permissible patient record created in hospitals that serve as the data source for all health records. It is an electronic version of a paper chart that includes the patient’s medical history, maintained by the provider over time, and may include all of the key administrative clinical data relevant to that persons care. Information that is readily available includesRead MoreWhy Code Is Outdated Or Outdated? Essay908 Words   |  4 Pageslook up information: ï‚ § The American Health Information Management Association or (AHIMA), if something isn t clear or more information. Also this website has new codes and their usage. AHIMA publishes a current listed of codes that is no longer in usage or supported. ï‚ § The American Optometric Association (AOA), provides doctor-reviewed, doctor-approved information about the greatest common eye conditions. III. FILING NUMBERING SYSTEMS A. What type of record filing system is used? Alphabetic

Friday, December 13, 2019

How I’Ve Changed over the Past Year Free Essays

How I Have changed over the past year? Humans are as changeable as the weather. Or perhaps a more frequent changer. And being one myself I’m no different. We will write a custom essay sample on How I’Ve Changed over the Past Year or any similar topic only for you Order Now Every night when I look back to the previous day I see no change. But when I look back to the year that has just passed, I do see the difference. The experiences I went through changed me to a better or may be something close to a reformation. Nevertheless I’m not the same anymore I was always known to be short-tempered and egoistic. But last year one incident really changed the way I was and thought. My sudden fluctuations in temper made me lose a lot of friends and the loneliness I was in taught me to be more friendly and patient. My friends always knew how to react to my rudeness but unfortunately I forgot my new friends were not accustomed to it. I met some buddies in a friend’s birthday party, last year, who were more than just casual acquaintances. One of them dropped coke over my new silk dress and that did it! I started yelling at her without noticing I am ruining the party. To my surprise the girl started crying and ran away while I was left standing clueless. The birthday boy came up and said â€Å"I think you better go wash yourself, Sunnu, before the spots get dry. I’ll call you later. † He never called and probably would not have if I had not met him in a mall a few days later. â€Å"Yes, I didn’t. But neither did you. † He answered when I asked why he did not call. â€Å"But you said ‘you’ will call. â€Å"Yes, but don’t you think you were at fault and should have taken the first step and said sorry? † I was very confused. I did not know what he meant. Why should ‘I’ be sorry? It was ‘her’ fault, not mines. But now I know why he did not. I was too egoistic to even think of being sorry, let alone saying it. She did a mistake unintentionally, but I did a bigger mistake by not doing what I should have done – forgive and forget. I realized this when one day one of my friends told me â€Å"Sunnu, you never accept the fact that even ‘you’ can make mistakes. You are always too angry to even think what other people might feel at your choice of words. † I was lonely. My friends had left me trying every possible ways to make me realize. But this lone feeling gave me time to think over everything and that is when I realized how wrong I was. One day, one week, one month and in a year I changed myself. I was a reformed Sunayna. I was better and the proof is all the old friends and many new ones happily smiling on the pictures in my â€Å"My Friends† album on Facebook. How to cite How I’Ve Changed over the Past Year, Papers

Thursday, December 5, 2019

Critical Reflection Is Essential For Developing Effective Practice Essay Example For Students

Critical Reflection Is Essential For Developing Effective Practice Essay ‘No one can consider themselves a professional unless they are prepared to engage in reflective activities’. Gardner 2006Critical reflection is essential in developing effective practice. Our own values and attitudes do come into play as individuals and as teachers. The trick is to first acknowledge that we have personal biases, identify where these are and work with them. O’Connor Diggins highlight that having reflective practice as a frame of mind assists educators in catching their own assumptions and exploring them rather than taking their biases for granted (Arthur et al. 2008, p. 138).Becoming a reflective teacher is going on a journey and becoming self-aware of our positives and negatives. According to Larivee (2009, p.19) part of being a reflective practitioner is to use ongoing inquiry, solitary reflection, perpetual problem solving and developing awareness. Nolan Raban (2015, p. 2) state that our assumptions shape practice which then determines how educators think and act. As teachers working in the early childhood sector, we will work throughout our careers with a vast variety of families and family structures, of which we may not agree with their personal values system or how they function as a family. Berk (2013, p. 566) insists in the context of moulding childrens’ development, nothing equals the family in power and total breadth of influence. According to Piaget children’s thinking shows their unique way of understanding and interpreting the world (Arthur et al. 2008, p. 92). Families do have a vision of their values and attitudes towards early childhood education, whether that is a firm belief, an assumption,or knowledge.. .007, n.p. ) having a critical framework is a guided progress, increasing potential for positive outcomes for the child, the family, the teacher and the wider community. Developing a personal culture of reflection and re-examining our values and biases takes strength, desire and constant adjustment. Engaging in reflective thinking involves educators to observe, listen, question and critique. According to Nolan Raban (2015, p. 67) a ‘community of practice’ is talking and thinking about practice by further exploration and reflection. Thinking critically encourages educators to be proactive, extending or refining an educator’s point of views. In the perfect world educators and families could all negotiate from an impartial point of view incorporating their current practices and strengths to equally co-exist in every child’s learning (Arthur et al. 2008, p. 583).

Thursday, November 28, 2019

The Bay of Pigs Invasion Essay Example

The Bay of Pigs Invasion Essay In April of 1961, the Central Intelligence Agency (CIA) supported and trained a group of Cuban refugees to invade Cuba, unfortunately the foray failed. Inside seventy-two hours of the initial assault, isolated from re-supply, the nearly two thousand American troops ran out of ammunition and were beleaguered by Cuban militia and army units.While President John Fitzgerald Kennedy publicly took responsibility for the events, investigations verified that the blame should have been placed exclusively in the hands of the CIA for not fully informing him of the crisis at hand. Regrettably, the extents of the consequences as a result of the failed invasion were yet to be fully recognized. Although the original confrontation was between the U.S. and Cuba, the threat of Russian action became a substantial factor. Overall, the Bay of Pigs invasion was helpless, useless and was disastrous for many reasons. The failed attempt wasted millions of U.S. dollars, time and resources, as it endangered an d costed the lives of more than eleven hundred soldiers. Questioning John Fitzgerald Kennedys ability as President, was the failure of the Bay Of Pigs Invasion. Due to the collapse of contact between the CIA and President John F. Kennedy in the invasion of the Bay of Pigs, an alliance between Cuba and the Soviet Union was allowed to arise and it powerfully tightened the tension between the United States and Soviet Union, because we attempted to invade one of their alliances. Hence, undermining the Soviets authority.The invasion force was unequal to the strength of Castros troops, and by April 19 its last stronghold had been captured, along with more than 1,100 men. The captured members of the invasion force were imprisoned. From May 1961 the Kennedy administration unofficially backed attempts to ransom the prisoners, but the efforts of the Tractors for Freedom Committee, headed by Eleanor Roosevelt failed to raise the $28,000,000 needed for heavy-co

Sunday, November 24, 2019

A Beginners Guide to Delphi Database Programming

A Beginners Guide to Delphi Database Programming About the Course: using TADOConnection Email Course Prerequisites: Delphi Programming A Beginners Guide to Delphi Programming Chapters Start with Chapter 1 : Then continue learning, this course already has more than 30 chapters ... CHAPTER 1:Fundamentals of Database Development (with Delphi)Delphi as the database programming tool, Data Access with Delphi...just a few words, Building a new MS Access database.related to this chapter! CHAPTER 2:Connecting to a database. BDE? ADO?Connecting to a database. What is the BDE? What is ADO? How to connect to an Access database - the UDL file? Looking forward: the smallest ADO example.related to this chapter! CHAPTER 3:Pictures inside a databaseDisplaying images (BMP, JPEG, ...) inside an Access database with ADO and Delphi.related to this chapter! CHAPTER 4:Data browsing and navigation Building a data browsing form - linking data components. Navigating through a recordset with a DBNavigator.related to this chapter! CHAPTER 5:Behind data in datasetsWhat is the state of data? Iterating through a recordset, bookmarking and reading the data from a database table.related to this chapter! CHAPTER 6:Data modificationsLearn how to add, insert and delete records from a database table.related to this chapter! CHAPTER 7:Queries with ADOTake a look at how you can take advantage of the TADOQuery component to boost your ADO-Delphi productivity. related to this chapter! CHAPTER 8:Data filteringUsing Filters to narrow the scope of data that is presented to the user.related to this chapter! CHAPTER 9:Searching for dataWalking through various methods of data seeking and locating while developing ADO based Delphi database applications.related to this chapter! CHAPTER 10:ADO CursorsHow ADO uses cursors as a storage and access mechanism, and what you should do to choose the best cursor for your Delphi ADO application.related to this chapter! CHAPTER 11:From Paradox to Access with ADO and DelphiFocusing on the TADOCommand components and using the SQL DDL language to help porting your BDE/Paradox data to ADO/Access.related to this chapter! CHAPTER 12:Master detail relationships How to use master-detail database relationships, with ADO and Delphi, to deal effectively with the problem of joining two database tables to present information. related to this chapter! CHAPTER 13:New...Access Database from Delphi How to create an MS Access database without the MS Access. How to create a table, add an index to an existing table, how to join two tables and set up referential integrity. No MS Access, only Pure Delphi code. related to this chapter! CHAPTER 14:Charting with Databases Introducing the TDBChart component by integrating some basic charts into a Delphi ADO based application to quickly make graphs directly for the data in recordsets without requiring any code. related to this chapter! CHAPTER 15:Lookup! See how to use lookup fields in Delphi to achieve faster, better and safer data editing. Also, find how to create a new field for a dataset and discuss some of the key lookup properties. Plus, take a look at how to place a combo box inside a DBGrid. related to this chapter! CHAPTER 16:Compacting an Access database with ADO and Delphi While working in a database application you change data in a database, the database becomes fragmented and uses more disk space than is necessary. Periodically, you can compact your database to defragment the database file. This article shows how to use JRO from Delphi in order to compact an Access database from code. related to this chapter! CHAPTER 17:Database reports with Delphi and ADO How to use QuickReport set of components to create database reports with Delphi. See how to produce database output with text, images, charts and memos - quickly and easily. related to this chapter! CHAPTER 18:Data Modules How to use the TDataModule class - central location for collecting and encapsulating DataSet and DataSource objects, their properties, events and code. related to this chapter! CHAPTER 19:Handling database errors Introducing error handling techniques in Delphi ADO database application development. Find out about global exception handling and dataset specific error events. See how to write an error logging procedure. related to this chapter! CHAPTER 20:From ADO Query to HTML How to export your data to HTML using Delphi and ADO. This is the first step in publishing your database on the Internet - see how to create a static HTML page from an ADO query. related to this chapter! CHAPTER 21:Using ADO in Delphi 3 and 4 (before AdoExpress / dbGO) How to import Active Data Objects (ADO) type-libraries in Delphi 3 and 4 to create a wrapper around components that encapsulate the functionality of ADO objects, properties and methods. related to this chapter! CHAPTER 22:Transactions in Delphi ADO database development How many times have you wanted to insert, delete or update a lot of records collectively wanting that either all of them get executed or if there is an error then none is executed at all? This article will show you how to post or undo a series of changes made to the source data in a single call. related to this chapter! CHAPTER 23:Deploying Delphi ADO database applications It is time to make your Delphi ADO database application available for others to run. Once you have created a Delphi ADO based solution, the final step is to successfully deploy it to the users computer. related to this chapter! CHAPTER 24:Delphi ADO/DB programming: Real Problems - Real Solutions In real world situations, really doing database programming is much more complex than writing about. This chapter points to some great Delphi Programming Forum threads initiated by this Course - discussions that solve problems on the field. CHAPTER 25:TOP ADO programming TIPS Collection of frequently asked questions, answers, tips and tricks about ADO programming. related to this chapter! CHAPTER 26:Quiz: Delphi ADO Programming What would it look like: Who Wants to be a Delphi ADO Database Programming Guru - the trivia game. related to this chapter! Appendices What follows is a list of articles (quick tips) explaining how to use various Delphi DB related components more efficiently at design and run time. APPENDIX 0DB Aware Grid ComponentsThe list of the best Data Aware Grid components available for Delphi. The TDBGrid component enhanced to maximum. APPENDIX ADBGrid to the MAXContrary to most other Delphi data-aware controls, the DBGrid component has many nice features and is more powerful than you would have thought. The standard DBGrid does its job of displaying and manipulating records from a dataset in a tabular grid. However, there are many ways (and reasons) why you should consider customizing the output of a DBGrid: Adjusting DBGrid column widths automatically, DBGrid with MultiSelect Coloring DBGrid, Selecting and highlighting a row in a DBGrid - OnMouseOverRow, Sorting records in DBGrid by Clicking on Column Title, Adding components to a DBGrid - theory, CheckBox inside a DBGrid, DateTimePicker (calendar) inside a DBGrid, Drop down pick list inside a DBGrid - part 1, Drop down list (DBLookupComboBox) inside a DBGrid - part 2, Accessing protected members of a DBGrid, Exposing the OnClick event for a DBGrid, What is being typed into the DBGrid?, How to Display Only Selected Fields in a DbGrid, How to get DBGrid Cell coordinates, How to create a simple database display form, Get the line number of a selected row in a DBGrid, Prevent CTRLDELETE in DBGrid, How to correctly use the mouse wheel in DBGrid, Making the Enter key work like a Tab key in a DBGrid ... APPENDIX BCustomizing the DBNavigatorEnhancing the TDBNavigator component with modified graphics (glyphs), custom button captions, and more. Exposing the OnMouseUp/Down event for every button.related to this quick tip! APPENDIX CAccessing and managing MS Excel sheets with DelphiHow to retrieve, display and edit Microsoft Excel spreadsheets with ADO (dbGO) and Delphi. This step-by-step article describes how to connect to Excel, retrieve sheet data, and enable editing of data (using the DBGrid). Youll also find a list of most common errors (and how to deal with them) that might pop up in the process. related to this quick tip! APPENDIX DEnumerating available SQL Servers. Retrieving databases on a SQL ServerHeres how to create your own connection dialog for a SQL Server database. Full Delphi source code for getting the list of available MS SQL Servers (on a network) and listing database names on a Server. related to this quick tip!

Thursday, November 21, 2019

Exploratory topic - i need a topic to get approval from the teacher Essay

Exploratory topic - i need a topic to get approval from the teacher this Sunday - Essay Example I do not want to malign the vast contributions of Apple to technology, but I want to take a step back and think about the negative effects of Apple on society. Apple has its dark side, which cannot and must not be overlooked. I wanted to learn more of how Apple managed to divide a potential one kind of product into several products. Apple consumers buy iPods, iPads, Macs, iPhones, and other Apple products, but do they truly need all these products? It seems that Apple has divided one product into several items, so that it can make more money in the long run. After all, its customers tend to think that they need an iPad too, even when their laptops suffice already. They buy more and more products, which in the end, increase garbage in society. I did some research on Apple’s wastes but cannot get specific details. I just focused on e-waste in general at first. I used the journal database to find answers and read the article â€Å"Mobile Phone Collection, Reuse and Recycling in the UK.† Ongondo and Williams describe how the short life cycle of high-tech products results to the vast bloom of e-waste production (1308). From this article, I learned that every year, new models of cellular phones a nd computing devices drive older models to obsolescence, thereby creating additional waves of e-waste. I wanted to learn more so I researched on what environmentalists have to say about Apple. I was surprised to know that they think that Apple is great polluter too. In â€Å"Apple Slammed by Greenpeace,† Deffree reports that environmentalist organization Greenpeace criticizes Apple for not responding to its recommendations with regards to removing hazardous chemicals in its products and employing progressive recycling policies (Deffree). I wanted more information, and I found another article that shares the same opinion. In the online article â€Å"Apple is creating an E-Waste Problem,† Biggs criticizes the 30-pin iPod port that was launched on

Wednesday, November 20, 2019

Acting and Performance in Films Term Paper Example | Topics and Well Written Essays - 1750 words

Acting and Performance in Films - Term Paper Example The profound performance by late Hollywood actor Heath Ledger puts life into the movie in a spectacular way that makes the actor and the movie both memorable to the audience. The social commentaries on the film contain few issues that are the key factors of controversy in this movie. The theme of romantic relationships between the two men is a primal point of focus in this film, which seems to rupture the conventional definition of relationship. The relationship that had sprouted long back between the two men could not come to its full bloom due to several social barriers. Ennis Del Mar (Heath Ledger) and Jack Twist (Jake Gyllenhaal) get married to, two women – Alma Beers (Michelle Williams) and Laureen Newsome (Anne Hathaway). The strain and ambiguity in relationship is clear from this action of the two men. Ennis Del Mar and Jack Twist are two farm associates, who are hired to take care of the thousands of grazing sheep, but these two men are extremely distinct by nature. Jack Twist is sparkling and emotional, while Ennis hardly talks, or frequently mumbles somewhat in a grumpy way. The ambience of a cold night, a little alcohol acts as the stimulant factors and they come across a sexual soiree that none of them ever expected. At a very young age, Ennis father had taught him about a firm example that tells the dire consequences that homosexuals face in the West. Therefore Ennis considers this incident as a one-time phenomenon. Jack is more certain about the feelings of this relationship and he is ready to explore them further. After their summer work comes to an end, they depart in their different ways and carry on their individual family lives. Ennis gets wedded and has two kids. Jack returns to the rodeo. After four years, they get back to each other, and are instantly set to revital ize their summer liaison. "Going fishing on Brokeback

Monday, November 18, 2019

Leading change at Corus Essay Example | Topics and Well Written Essays - 3000 words

Leading change at Corus - Essay Example Leadership effort must therefore support and build organization members particularly employees to understand leadership agenda in managing change and play their role within the sphere of their activities (Black & Hal 2002, p. 91). Implementing change sometimes require sense of urgency. Of great importance is to understand change, drivers and barriers of change and identify strategies and initiatives geared towards leading change effectively. This study explores and examines changes that have occurred at Corus, how the company has managed them, barriers that have been faced concerning change and reasons for the changes. Corus Tata Steel Group is world’s sixth largest producer of steel. Corus forms part of the group in Europe being the second largest producer of steel in Europe with approximately  £12 billion annual revenue. Corus produces over 20 million tons annually in U.K. and in Netherlands. The company has global network of service centres and sales offices employing about 42,000 staff across globe (Corus, 2010). Corus has been a leader in supplying steel to various markets across the globe. Long Products Business is Corus’ business unit that manufactures steel in France, Scotland and England. The three units produce various steel products that range from wire rod to steel plate to steel rail. Key markets for the Long Products Business include engineering, construction, mining, machinery, earthmoving equipments, fastening, rail and ship building. Continuous improvement gives business a competitive advantage enabling it to stick ahead of its competitors and also increase market share. Good use of experience and skills enables organizations to enhance better products and processes. In the context of Corus, the company uses continuous improvement to drive new and innovative products development and meet customers’ needs (Corus, 2010). Continuous improvement practices have enabled Corus to solve problems that face its steel works and win great contracts. Continuous improvement practices coupled with the dynamic market environment gives forth to new products development and changes in the business process across the company’s divisions and department. Corus is thus challenge to come up with a way of managing the inevitable change. External environment operated in keeps on changing and businesses are challenged to respond on time and appropriately to the changes faced in order to secure their competitiveness. Change management requires support from various business stakeholders including management, employees, shareholders and suppliers among others. Suc h cooperation ensures that the changes made remain embedded to the shaping of the firm. In the context of Corus, the company launched a culture plan through the Corus Strip Products or the CSP team in UK (Corus, 2010). This plan focused on change management and was dubbed ‘The Journey’. The aims of the company were to address wide business challenges and how people carried out work. The plan focused on beliefs and values of the organization members as well as suppliers and partners. The eight core values defined by the plan guides Corus and offer its members the guiding principles. CSP Journey outlined behaviours and values that Corus expected members to follow and encouraged them to remain accountable. Some of the issues the plan aimed at eliminating included tragic accidents occurring on site among other safety and health issues. CSP Journey underpins the company’s culture and has given Corus U.K. a positive approach.

Friday, November 15, 2019

Using Thin Layer Chromatography To Monitor Reactions Environmental Sciences Essay

Using Thin Layer Chromatography To Monitor Reactions Environmental Sciences Essay Thin layer chromatography (TLC) is a very useful technique for monitoring reactions. It can also be used to determine the proper solvent system for performing separations using column chromatography. TLC stationary phases are usually alumina or silica. They are polar for standard experiments or non-polar for reverse phase chromatography. The mobile phase is a solvent whose polarity is chosen by the person conducting the experiment. In most laboratory work standard phase silica plates are used. Different compounds will travel different distances up the plate depending on the polarity of the components of the mixture. The more polar compounds will be more attracted to the polar silica gel and travel shorter distances on the plate. Mon-polar substances will spend more time in the mobile phase and as a result will travel larger distances on the plate. The measure of the distance a compound travels is called the retention factor (Rf ) value. The retention factor, or Rf, is defined as the distance traveled by the compound divided by the distance traveled by the solvent. For example, if a compound travels 2.1 cm and the solvent front travels 2.8 cm, the Rf is 0.75: The Rf for a compound is a constant from one experiment to the next only if the chromatography conditions below are also constant: solvent system adsorbent thickness of the adsorbent amount of material spotted temperature Since these factors are difficult to keep constant from experiment to experiment, relative Rf values are generally considered. Relative Rf means that the values are reported relative to a standard, or it means that you compare the Rf values of compounds run on the same plate at the same time. 1.1 Thin Layer Chromatography There have been a numbered of important milestones in the evolution of chromatography in the last 100 years. Each of these milestones has signalled the start of an important branch of chromatography. Some examples of these are; partition chromatography (1941), gas chromatography (1951-1952), high performance liquid chromatography (mid- 1960s), capillary electrophoresis (1980) and capillary electrochromatography (past decade). In all the chromatographic techniques mentioned, separation is carried out in a column. However, it is also possible to carry out separations on a planar surface. Two examples of this are paper chromatography (1944) and thin-layer chromatography (1937-1938). Thin-layer chromatography (TLC) replaced paper chromatography as the most popular, routine chromatographic technique. TLC was first used in 1937 to 1938 by Nikolai A. Izmailov and Maria S. Shraiber at the Institute of Experimental Pharmacy of the State University of Kharkov. At the time Izmailov was the head of the institute and Shraiber was his graduate student. They were searching for a method for the rapid analysis of galenic pharmaceutical preparations (plant extracts). As classical column chromatography would have taken too much time they felt that if the absorbent would be prepared in the form of a thin-layer on a glass plate. They believed that it would behave like a column but the characterization time would be much shorter. They coated microscope slides with a suspension of various adsorbents (calcium, magnesium and aluminium oxides). They deposited one drop of the sample solution on this layer and added one drop of the same solvent used in a column to develop separation. The test was a success as the separated sample components appeared as concentric rings that fluoresced in various colour s under a UV lamp. They showed that the sequence of the concentric multicoloured rings on the plate would have been identical to the sequence of coloured rings obtained on a normal chromatographic column. They called this technique spot chromatography and the result on the microscope slides ultrachromatograms. The paper on this experiment was published in a Russian pharmaceutical journal that was practically unknown outside the then Soviet Union. Its abstract was included in a Russian review journal and through it in chemical Abstracts. It was then read by M. OL. Crowe of the New York State Department of Health. He then adapted the technique for his own use. Crowe prepared the adsorbent layer in a Petri dish, added a drop of the sample solution in the centre and then added the developing solvent dropwise until sufficient separation was obtained. In 1947 T.I. Williams described a further improvement of the method of Izmailov and Shraiber in his textbook on chromatography. He prepared the adsorbent-coated glass plates in the form of a sandwich. The adsorbent layer was covered by 2 glass plates and had a small hole which the sample drops could be applied through. Meinhard and Hall made the next major step in the development of TLC at the University of Wisconsin. They used corn starch, which acted as a binder, to hold the coating on the glass plate and added a small amount of Celite powder to the adsorbent particles to improve the consistency of the layer. They called this surface chromatography. They used it to separate inorganic ions. Modern TLC started 50 years ago with the work Department of Agriculture Fruit and Vegetable laboratory in Southern California. He investigated the flavour components of the juices of citrus fruits. However, he stated that very large volumes had to be processed because the amount of flavour material was extremely small. Another problem was in finding an analytical method for the investigation of the juice concentrate composition. He followed the method of Meinhard and Hall that he read in Chemical Abstracts. However, instead of adding just a drop of the developing solvent he developed the plates as in paper chromatography. The plates were developed in a closed chamber and one side was dipped into the solvent. The solvent then ascended through the plate by capillary action. It carried with it the sample components and they were separated as a result. The experiments carried out were published and are considered the start of modern TLC. Egon Stahl was responsible for TLC becoming a universally accepted technique. He was also the first to use the term thin-layer chromatography to characterize the technique. This choice of name was almost immediately accepted. Stahl investigated various essential oils and obtained good results using adsorbent-coated glass plates. However, neither the method nor the adsorbent to be used had been optimized. Also, the adsorbents had to be modified and treated before they could be used for the coating of plates. Stahl started investigating the operational parameters and the adsorbent preparations. In the spring of 1958 his efforts were fulfilled as the necessary basic instrumentation, made by Desaga and silica gel G according to Stahl for TLC, made by E. Merck were both introduced at the international Achema exhibition of chemical equipment in Frankfurt. Stahl also published an article outlining the use of the system and a wide range of applications. Because of this standardized method TLC became a widely used laboratory technique. He also went on to publish a TLC handbook in 1962. Although TLC had a wide application it was still thought to be a qualitative technique for the analysis of simple mixtures. As a result advances were directed toward improving the technique. Instrumentation which permitted more precise spotting of the sample onto the plates and the quantitative evaluation of the separated spots was developed. Faster analysis and higher separation power was also achieved. As a result of the higher performance ability the name was change to high-performance TLC (HPTLC) by R.E. Kaiser, who was instrumental in its development. The particle size and range of the adsorbent was the main difference between TLC and HPTLC. The silica gel for TLC had broad particle sizes of 10-60 µm with an average of 20 µm whereas HPTLC has an average of only 5 µm. the HPTLC plates were also smaller in comparison with TLC plates, 10 x 10cm and 20 x 20cm respectively. The improved method and design allowed reduction in the diameter of the starting spots. These improvements lowered the analysis time and increased the efficiency. Problems arose with flow rate which Kaiser overcame by applying pressure to the TLC plate. This in turn led to forced-flow TLC. Due to the constant condensation-evaporation process associated with developing TLC plates in developing chambers problems can be encountered because of the changing velocity of the mobile phase. To overcome this forced-flow TLC (FFTLC) was developed by Tyihà ¡k, Mincsovics and Kalà ¡sz. In this method the spotted plates (dry) are placed into a pressurized development chamber. The stationary-phase layer is tightly covered and sealed on its side by an elastic membrane and pressurized by an inert gas or water filling up the cushion above the layer. The mobile phase is delivered via a pump at a constant velocity through a slit in the membrane to the stationary phase. There are various configurations which can be handled using this method. TLC is a very simple technique. As a result very little instrumentation is needed. Application of samples to the stationary-phase is carried out using a micropipette or syringe. The developing chambers are simple glass structures. Detection is carried out by visual inspection or made visible by spraying the plate with reagent. Also, a wide variety of precoated plates are available so coating equipment isnt needed. In more advanced systems the samples may be spotted by automated loading devices (dosimeters). This allows the application of small and uniform sample spots. More sophisticated developing chambers are also available (FFTLC). The plates can be scanned by densitometers and quantitatively analysed using absorbance or fluorescence measurements. Chromatograms with peaks of the individual separated spots recorded against the length of the plate are produced with such analyses. Their area is also a proportion to the amount present. More complex systems can also be created by combining TLC systems with other systems such as mass spectrometry and Fourier transform infrared. 1.2 Ink Analysis Ink analysis is a very important forensic procedure. It can reveal useful information about questioned document. Modern inks contain many substances which are aimed at improving the ink. The most important component of the ink is the colouring material. It comes in the form of a dye, pigment or a combination of both. Dyes are soluble in the liquid body of the ink, also known as the vehicle. Pigments are finely ground multi-molecular granules that are insoluble in the vehicle. The vehicles composition affects the flowing and drying characteristics of the ink and can consist of oils, solvents and resins. 1.3 Chromatography Studies Djozan et al developed a new and fast method for the differentiation of inks on a questioned document. They designed specific image analysis software for evaluating thin layer chromatograms. They sampled forty-one blue ballpoint pens which were purchased from their local markets in Iran (Table 1). They first wrote a circle of diameter 5 mm uniformly by pen on a paper. One fourth of this was then punched out for extraction. They carried out extraction in 1 ml glass tubes and added 0.1 ml of methanol. This was then vigorously shaken for 1 min. the ink component was then fully dissolved in methanol. The supernatant methanoic solutions were then used to spot the TLC plates. A blank sample of paper with equal dimensions was also treated in the same way. Table 1. List of blue ballpoint pens studied List of blue ballpoint pens studied 1 Cello pyramid 0.7 mm fine TC ball 2 OBA 3 AIHAO 4 Bic 01 5 Cenator 6 PARKER 7 A.T.CROSS FINE 8 Pelikan STICK 918 9 Marvy SB-10 1.0 mm 10 Bic 02 11 PIANO crystal 12 My pen 2001 PENS High Quality Bluce CE 13 AIBA 14 STAEDTLER Stick 430M A IRAN 15 Reynolds Medium 048 France 16 EIFEL Elegance 17 CASPIAN STICK 2001 M 18 STABILO liner 308 19 FABER-CASTELL 1.0 mm Medium (transparent) 20 BIC 08 21 Bocheng A-100 22 SCHNEIDER TOPS 505 M Germany 23 FIBER-CASTELL 1.0 mm Medium 24 MILAN PI 1 mm 25 Reform 26 PAPER = MATE FLEXGRIP ultra MED 27 PARKER UK 28 CANDID-DINI 2853 29 STABILO-galaxy 818 M 30 No name 31 No name 32 Zebra Rubber 101 33 SANFORD SAGA 34 Bensia 35 Girls 36 EUROPEN 37 PARS swiss Refill 606 38 STAEDTLER stick 430 M TBRITAIN 39 Lus HF 500 40 No name 41 STABILO bill 508 TLC analysis was carried out on Merck (Darmstadt, Germany) 20 cm x 20 cm silica gel 60 TLC plates without fluorescent indicator. The plates were activated at 60  °C for 20 min and immediately spotted after cooling in a desiccator. The plates were developed in a developing chamber. The mobile phase used was: ethyl acetate/ absolute ethanol/ distilled water (70:35:30, v/v/v). Chromatographic development of the plates was carried out at room temperature for 40 min. All mobile phases were prepared daily with analytical grade chemicals. Enough was prepared to supply the tank for each run. The plates were air-dried after development. The separated compounds were visible on the plate by their natural colour and the plates were scanned into a computer using an office scanner. An IBM compatible PC (Pentium IV) with a 2.6 GHz microprocessor, 256 MB random access memory (RAM) and a hard disk with 40 GB capacity for external storage was used for processing the colour images. The computer was equipped with an on-board graphic card (NviDiA Geforce 7300LE) and a scanner (CanoScan 4200F) was connected to the computer for scanning (300 dpi) TLC plates as digital images. The images were saved as bmp files. Matlab (Version 6.5, The Math Works, Inc.) was used to write a new program to process the previously saved images. Previous studies indicated that Pyridine is the solvent used with ballpoint pen inks. Djozan et al preformed extraction with different solvents using various extraction modes. These modes were immersion of paper into solvent and simple agitation for 1 min, ultra-sound assisted extraction and micro-wave assistance extraction. The results showed that the immersion of paper into methanol or pyridine and simple agitation resulted in complete extraction of the inks from paper (Table 2). Table 2. List of solvents used for extraction of ink components from paper Solvent Solubility of ink colours Ethyl acetate Ethanol Acetic acid Acetone Butanol 1,2-Dichloroethane Butyl acetate Tetrachloroethane Acetyl acetate Cyclohexane Methanol Pyridine Slightly Slightly Slightly Slightly Slightly Slightly Slightly Slightly Slightly Slightly Soluble Soluble No improvement was found using ultra-sound or micro-wave assisted extraction. Methanol was chosen as the extraction solvent due to the safety of the solvent. The selection of the plate was down to the fact that silica gel plates provided the best resolution of dye spots. They selected five mobile phases (Table 3) and found that ethyl acetate/ absolute ethanol/ distilled water (70:35:30, v/v/v) was effective in separating nearly all the dye mixtures. The spot capacity obtained was more than 15. Table 3. Different solvent systems used to develop plate Solvent System Ratio Spot capacity Butanol:ethanol:H2O Ethyl acetate:cyclohexane:methanol:NH3 Ethyl acetate:Butanol:NH3 Ethyl acetate:ethanol:H2O Toluene:acetone:ethanol:NH3 50:15:10 70:15:10:5 60:35:5 70:35:30 30:60:7:2 9 5 10 15 5 Fig. 1. Typical TLC results of 10 different ink samples (Djozan et al, 2008) Fig. 1. shows a typical chromatogram that they achieved in their experiment. To confirm complete separation of all components in the studied sample, two-dimensional (2D) TLC was carried out using various solvent systems. The results proved that the one-dimensional (1D) TLC is able to provide sufficient separation. The first stage carried out was colour image normalization. A function of the input images was computed that is invariant to confounding scene properties but was discriminative with respect to desired scene information. The calculation is as follows: Stage 2 is to compute a colour image profile. The intensity profile of an image is the set intensity values taken from regularly spaced points along a line segment in an image the intensity values are interpolated for points that dont fall on the centre pixel they computed an intensity profile for r, g and b images along the line passing through the centre of the image on the chromatographic development straight of each ink spot. Fig. 2. RGB characteristic of an ink after TLC (Djozan et al, 2008) In stage 3 the colour image profiles were correlated. The intensity profiles were considered as sequences and the normalized cross-correlation of sequences were computed. Cross-correlation is a measure of similarity of two signals. It is used to find features in an unknown signal and compared to a known signal. It is calculated as follows for discrete functions: Eq. (1) For image-processing applications in which the brightness of the images can be due to lighting and exposure conditions, the images can be first normalized. It is calculated as follows: Eq. (2) Stage 4 involved computing image similarity. The weighted mean of and were computed as follows: Eq. (3) The ability of the method to differentiate between various blue ballpoint pens was evaluated by comparing the similarity of different inks according to Eq. (3). Fig. 3. Screen shot of Matlab software running (Djozan et al, 2008) Fig. 4. All possible combination of comparing inks with TLC-IA (Djozan et al, 2008) In 2006 Liu et al published a paper on the classification of black gel pen inks by ion-pairing high-performance liquid chromatography. They stated that black gel inks usually contain several dye components. These components all have different colours and are mixed together proportionally to give the black colour. They used reverse-phase ion-pairing high performance chromatography (RP-IP-HPLC). It was done in such a manner as the dyes couldnt be reversed on the C18 column due to their high polarities. The maximum UV absorption bands of the black gel pen inks obtained were between 500 and 700 nm. The wavelength of the detector was set to 580 nm as most of the dyes had a maximum UV adsorption near 580 nm. They investigated the influence of both volatile and non-volatile ion-pairing reagents on the HPLC analysis of black gel pen ink dyes. All the reagents had different alkyl chain, ammonium acetate, triethylamine (TEA), tributylamine (TBA), dihexylamine (DHA) and tetrabutylammonium bromide (TBABr). The results revealed that the dyes were nearly not retained using ammonium acetate or TEA as the ion-pairing reagent. Using TBABr, TBA and DHA as the ion-pairing reagent, individually, the dyes were separated. TBABr was selected as the ion-pairing reagent as the retention times were shorter than the others and sharper peaks were obtained. They also investigated the buffer solution concentrations and the effect of pH on the separation. The optimum result was: 40 mmol/L TBABr buffer solution (pH 7) with acetonitrile as the organic modifier for IP-HPLC analysis and an identical proportion of the buffer and acetonitrile (v/v = 40:60) at a flow rate of 1.0 mL/min. these optimum conditions were used to separate 50 dye-based black gel pen inks by IP-HPLC. Liu et al carried out another study on ion-pairing HPLC in 2006. This time, however, they studied the degradation of blue gel pen dyes and also used electrospray tandem mass spectrometry. They used ion-pairing reversed phase liquid chromatography as the inorganic compounds they were analysing have weak retention on the ordinary reversed stationary phases when separating on HPLC. This is due to their high polarities. The UV detector was set at 580 nm for the analysis as most dyes have a normal maximum absorption near 580 nm. The UV absorptions of the fluorescence whitening reagents in paper are usually below 500 nm and they had no interference for the detection of the gel pen dyes at 580 nm. Fig. 5. Chromatograms of blue gel pen inks using different ion pairing reagents (Liu et al, 2006) The tested various mobile phases: eluent A: eluent B (acetonitrile) = 50:50 (v/v); eluent A was the buffer of ion pairing reagent with concentration of 40 mmol Là ¢Ã‹â€ Ã¢â‚¬â„¢1 (pH 7.0), and the ion pairing reagent was (a) ammonium acetate, (b) TEA acetate, (d) TBA acetate, (e) DHA acetate and (f) TBABr, respectively. (c) Ammonium carbonate as eluent A (40 mmol Là ¢Ã‹â€ Ã¢â‚¬â„¢1, pH 9.5) and eluent A:eluent B (acetonitrile) = 50:50 (v/v). they found that 10 mmol-1 TBA acetate (pH 7.0) was suitable ion-pairing agent for the purpose and ink samples stored in different conditions were analyzed by IP-HPLC. Significant changes of ink composition were observed. The noticed that the natural aged inks had the similar but weaker degradation trend than the light aged inks. They used HPLC-MS/MS with ammonium carbonate as ion-pairing reagent to obtain the information of the light aged inks and their photodegradation mechanism. In 1994, Varshney et al analysed ink from typed script of electronic typewriters by HPTLC. They used script from seven electronic typewriters. They used the resultant Rf values and in-situ visible spectra of each resolved band of all the chromatograms indicated that the same chemical composition is being used in six typewriter ribbon inks. However, the seventh one is completely different. Fig. 6. Wavelength maxima values of in-situ visible spectrum bands of electronic typewriter scripts (Varshney et al, 1994) Fig. 6. shows the densitograms obtained after scanning and integration of the chromatograms of tracks of individual typewriters and blank paper. The seven electronic typewriter inks could be categorised into two groups after analysis. The first group resolved the sample to four bands including the base. The second group did not resolve the samples at all with the solvent systems used. Several varieties of blue ballpoint pen inks were analysed by HPLC and IR spectroscopy by Kher et al in 2006. The chromatographic data extracted at four wavelengths (254, 279, 370 and 400 nm) was analyzed individually and at a combination of these wavelengths by the soft independent modeling of class analogies (SIMCA) technique. They used principal components analysis (PCA) to estimate the separation between the pen samples. Linear discriminant analysis (LDA) measured the probability with which an observation could be assigned to a pen class. The best resolution was obtained by HPLC using data from all four wavelengths together, differentiating 96.4% pen pairs successfully using PCA and 97.9% pen samples by LDA. PCA separated 60.7% of the pen pairs and LDA provided a correct classification of 62.5% of the pens analyzed by IR. They stated that HPLC coupled with chemometrics provided a better discrimination of ballpoint pen inks compared to IR. Kher et al effectively combined LDA and PCA to classify the HPLC and IR data. PCA gives a general idea of how different a given pair of pens is, whereas LDA can quantify the predictive ability of a generated classification model. The two techniques of PCA and LDA were shown to be complimentary to each other. The PCA and LDA results indicated that although IR cannot differentiate between all classes of pen inks, it can still provide a reasonable discrimination, which can be enhanced further by improving the quality of the spectra. The analysis of such an enhanced IR data with chemometric analyses would provide a valuable non-destructive tool for forensic analyses. Raman Spectroscopy Studies Mazzella and Buzini used Raman spectroscopy to analyse blue gel pen inks in 2004. They sampled 55 blue gel pens. They first separated them into two groups using a preliminary solubility test in methanol. They discovered that 36 were pigmented inks, which arent soluble in methanol, and 19 were dye-based inks, which are soluble in methanol. They applied Raman spectroscopy to the 36 pigmented blue gel inks. Raman spectroscopy is a non-destructive technique. Spectra were first obtained using the 514.5 nm argon ion laser which proved the observation of 4 different groups. They then used the 830 nm NIR diode laser and divided the inks into three groups. They then combined the two lasers and a separation into 5 groups was obtained. They then attempted to identify the pigments contained in the gel by comparison to standard pigments. Two main pigments were detected in the analysed samples: PB15 and PV23. PB 15 is pigment blue 15 and belongs to the class of phthalocyanines. PV23 is the pigment violet 23 and belongs to the class oxazines. The argon laser allowed the detection of a mixture of PB 15 and PV 23. This was a better result than using the NIR diode laser. The results showed that the same gel pen ink (same model and brand) from different geographical locations showed the same Raman spectra. However, it was stated that the Raman technique obtained low discriminating values. 2. Materials and Method 2.1 Materials: Blue ballpoint pens Merck silica gel 60 TLC plates (20 cm x 20 cm) Methanol Ethyl acetate Ethanol (absolute) Paper Dessicator Developing chamber Puncher Glass tubes (0.1 ml) Capillary tubes 2.2 Experimental 13 blue ball-point pens (Table 1) were bought from a number of different shops in the town. A circle with a diameter of 5mm was written by the pen on paper. One fourth of it was punched out for extraction. The samples are placed in 1 ml glass tubes. 0.1ml of methanol was added and vigorously shaken for 1 min. The ink component was fully dissolved in methanol. The supernatant methanoic solutions were used for spot application on TLC plate. A blank of paper only is also treated as was a control which was a permanent marker. TLC analyses were preformed using Alugram 20 cm x 10 cm silica gel/UV plates (Macherey-Nagel). The plates were activated at 60 °C for 20 min and immediately after, cooled in a desiccator, and spotted. The plates were developed in a horizontal developing chamber. The solvent system included: ethyl acetate/absolute ethanol/ distilled water (70:35:30, v/v/v). Development was preformed at room temperature for 40 min. All mobile phases were prepared daily. After develo pment the plates were air-dried. All 13 different pens were tested in triplicate. Retention factors were calculated using the results from the plates and photographs taken using a digital camera were loaded onto the computer and analysed using image analysis software. Table 1: List of pens analysed Number Description 1 No Brand (blue) 2 Pilot G-207 3 BIC ReAction 4 BIC Medium (Bought in Tesco) 5 BIC Medium (Bought in Dunnes) 6 No Brand (Purple) 7 Staedtler Stick 430M 8 Roller Pen 9 Papermate 1.2M 10 Scripto Stick Pen 11 Papermate Write Bros. 12 Comfort Touch 13 No Brand (Tesco Click Pen) 3. Results and Discussion Before carrying out the experiment it needed to be researched. This research pointed out the importance of the correct solvent to remove the ink from the document. Djozan et al used methanol as their choice of solvent after considering other solvents (Table 2). They stated that Pyridine was the reported solvent used with ball-point pen inks. However, they carried out extractions with different solvents using various extraction modes. They realised that immersion of the paper into methanol with agitation resulted in complete extraction of the inks from the paper. Methanol was also chosen because of its safety. Table 2: List of solvents used for the extraction of ink components from paper Solvent Solubility of ink colours Ethyl acetate Slightly Ethanol Slightly Acetic Acid Slightly Acetone Slightly Butanol Slightly 1,2-Dichloroethane Slightly Butyl acetate Slightly Tetrachloroethane Slightly Acethyl acetate Slightly Cyclohexan Slightly Methanol Soluble Oyridine Soluble Different concentrations of the solvent system (Table 3) were analysed to see which gave the greater separation. It was found that the concentration given by Djozan et al, (ethyl acetate, ethanol, and water (70:35:30, v/v/v)) gave the best results. The Alugram silica Gell/UV plates were also found to work better than the suggested, Merck silica gel 60, plates without fluorescent indicator. Table 3: Concentrations of solvent system investigated Number Solvent system 1 ethyl acetate, ethanol, water (70:35:30, v/v/v) 2 ethyl acetate, ethanol, water (70:30:35, v/v/v) 3 ethyl acetate, ethanol, water (70:25:40, v/v/v) 4 ethyl acetate, ethanol, water (70:40:25, v/v/v) Table 4: Retention factors for all separated components pen spot 1 spot 2 spot 3 spot 4 spot 5 Solvent RF1 RF2 RF3 RF4 RF5 1.1 70 73 0.958904 1.2 70 73 0.958904 1.2 70 73 0.958904 2.1 62 69 73 0.849315 81.24194 2.2 62 69 73 0.849315 81.24194 2.3 62 69 73 0.849315 81.24194 3.1 57 60 62 70 0.814286

Wednesday, November 13, 2019

Dehumanization in Death of a Salesman Essay -- Death Salesman essays

Dehumanization in Death of a Salesman      Ã‚   Alienation and loneliness are two of the frequently explored themes in Arthur Miller’s Death of a Salesman.   Yet they can also cause other effects which are just as harmful, if not more so.   In Death of a Salesman, two of these other results are dehumanization and a loss of individual freedom.   This is a very complex web of emotions, but as Miller said, â€Å"Death of a Salesman is not, of course, in the realistic tradition, having broken out into quite a new synthesis of psychological and social dimensions† (Eight vii).   It did indeed â€Å"break out† in the modernist direction.   It is a wonderful example of the way modernist writers expressed their beliefs.   They believed that the industrialization of society caused people to lose their individuality.   Willy’s seniority at his advertising firm means very little in the larger scheme of things.   He is just one of the many workers.   He begins to wear out and be of little use.   Therefore, he is discarded and presumably replaced with someone who will do the job more efficiently.   He is not treated as a human being but as a part of a larger mechanism, a larger machine.   This crushes what little self-esteem he has left.   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   This mechanized society can also lead to a loss of individual freedom.   In order to survive, one must be a part of the competitiveness.   This may mean giving up having the freedom to choose a pleasing occupation.   Biff wants to find his own way and do what he wants; he is looked down upon because of his wish.   Happy, his brother, wants to be financially successful.   He knows that in order to do that, he needs to join the work force and persevere where his father failed.   In this society, one can either do what he ch... ...g the Loman family, Miller relates the larger, all encompassing themes of the modernists to a common American family.   Miller relates them, specifically Willy Loman, to society as a whole and to the smaller societal unit of the family.   He then goes on to show the psychological responses to and results of societal conditions.   Specifically, he demonstrates that interaction with modern society without some understanding of what is occurring can lead to alienation and loneliness.   These, in turn, can lead to dehumanization and a loss of freedom for the individual.    Works Cited Baym, Franklin, Gottesman, Holland, et al., eds.   The Norton Anthology of American Literature.   4th ed.   New York: Norton, 1994. Florio, Thomas A., ed. â€Å"Miller’s Tales.† The New Yorker.   70 (1994): 35-36. ---.   Eight Plays.   New York:   Nelson Doubleday, 1981.         

Sunday, November 10, 2019

Lodge’s narrative technique Essay

Abstraction: David Lodge ( 1936- ) is extremely respected and regarded as a critic and author who is profilic in both Fieldss in modern British. As a author. David Lodge is chiefly celebrated for his academic novels particularly his Campus Trilogy: Changing Topographic points. Small World and Nice Work in 70-80 in the 20 century. Campus Trilogy is regarded as the research object in the paper. This thesis attempts to do a comprehensive survey of Campus Trilogy from Narratology Angle. It wonders to detect the undetected deduction in the narrative plants to make full the space in this country of research by the macroscopic analysis and microscopic examination. The thesis consists of four chapters. Introduction includes a brief debut to David Lodge. his literary accomplishments. his representative plants Campus Trilogy. its literary reappraisal and the significance of the thesis. In add-on. the constructs and methods are merely presented. Chapter I outlines Narrative Structure of Campus Trilogy. By set uping the binary opposite smudge construction in the clip and infinite which lays out intricately. it makes the fresh fascinating but needs readers to read the novels caregully. Chapter II demonstrates Campus Trilogy from Narrative Perspective. The writer organizes the different focal point manners to run into the author’s need by agencies of different characteristics of the focal point manners. This refelcts Lodge’s academic point of views from one side: oppose the Jacobinic sentiment of The Death of Author. Lodge uses the altering focal point to do you cognize what he wants you to cognize and and hide what he doesen’t want you to cognize. It gives the readers to conceive of and think. Meanwhile the narrative voices in Lodge’s novels are. fro one clip. individual. for other clip. multi-voices with those of the existent writer. implied writer. storyteller. and characters. He manages the diffi cult and soft voices as per the demands of his plants. Chapter III trades with the Meta-fiction narrative techinque utilizing in Campus Trilogy. The writer masters the accomplishment of Parody and Collage to interrupt the true consequence of the narrative. It exposes the fiction of the novels by itself and subverts the readers’expectation. Otherwise it makes the reader maintain the critical attitude to believe the relationship between the world and novelistic. Chapter IV explores the narrative technique of Irony in Campus Trilogy. Lodge hides his point of view by puting the dry characters. sarcasm of state of affairs and dry allusions. Readers are in aesthetic. emotional and ethical multiple state of affairss and dry allusions. The kernel of the manner to success of the bookmans is making the primitve and coarse natural degree of being. They achieve slef-destruction successfully. They lost the humanity spirit non merely owing to the infinite enlargement of the economic system. but besides the divergence and treachery of the humani stic disciplines bookmans. In a word. though Lodge’s novels contain the deep implied significances. they have the strong readability. On the one manus. David Lodge indulges himself to the assorted experimental accomplishments of Meta-fiction. so some of the critics classify him to be a post-modernism novelist. On the other manus. as a traditional author. he has a pots of historical and societal mission. He doesn’t give up the basic traditional realist. The scholar life in Campus Trilogy is based on his ain personal experience or the familliar personal businesss around. It makes the readers know the life of the schilars in the Ivory Tower. In the average clip. his novels reveal the degeneracy of the humanity in the modern society. Consequently his Campus Trilogy hovers among pragmatism. modernism. and post-modernism but non simple post-modernism narratology.

Friday, November 8, 2019

Majority Government in Canada

Majority Government in Canada The way Canada elects its representatives and head of government is different from the process we follow in the United States. Winning a majority of seats in the Canadian Parliaments House of Commons has different ramifications than winning a majority in the U.S. Senate or House of Representatives. In our presidential system, the head of state and the head of government is the same  person, and he or she is elected independently of the members of the American legislature (Senate and House of Representatives). But in a parliamentary system, theres a head of state and a head of government, and the head of government derives its power from the ruling party. In Canada, the head of state is the Queen, and the prime minister is the head of government. The ruling party determines who will be prime minister. So how does a party become Canadas ruling party? Majority Party Versus Minority Party in Canada The political party that wins the most seats in a general election becomes the governments ruling party. If that party wins more than half of the seats in the House of Commons or legislative assembly, then the party forms a majority government. This is the best-case scenario as far as a political party is concerned (but may not be ideal for voters, depending on how they voted), since it ensures they will be able to steer the direction of policy and legislation without much input (or interference, depending on your point of view) from other parties.  The parliamentary system of government makes party loyalty from Canadian politicians  all but assured. Heres why: A majority government can pass legislation and maintain the confidence of the House of Commons or legislative assembly to stay in power much more easily than a  minority government. Thats what happens when a party wins half or fewer than half of the seats in the House of Commons or legislative assembly.   In order to retain the confidence of the House of Commons and remain in power, a minority government has to work a lot harder. It will have to negotiate more frequently with other parties and possibly make concessions and adjustments in order to win enough votes to pass legislation.   Choosing Canadas Prime Minister The entire country of Canada is divided into districts, also known as ridings, and each one elects its representative in Parliament. The leader of the party that wins the most ridings in a general federal election becomes Canadas Prime Minister.   As head of the countrys executive branch, Canadas prime minister chooses the cabinet, deciding who should oversee the various government departments, such as agriculture or foreign affairs. Most of Canadas cabinet ministers come from the House of Commons, and occasionally one or two come from the Senate. The prime minister serves as chairman of the cabinet. Canadian federal elections are usually held every four years on the first Thursday in October. But if the government loses the confidence of the House of Commons, a new election may be called.   The political party which wins the second highest number of seats in the House of Commons becomes the official opposition party.   The prime minister and cabinet are the key decision-makers in Canadian government. Having a majority party makes their jobs much easier.

Wednesday, November 6, 2019

Simon Bolivar essays

Simon Bolivar essays The Generals Disunited States of South America Let us hasten to break the chains of those who groan in the dungeons waiting for salvation from you. Do not betray their trust. Do not be deaf to the cries of your brothers. Avenge the dead, save the dying, relieve the oppressed, and bring freedom to all! Those were the powerful words written by Simon Bolivar, which persuaded the people of Colombia to support him with the liberation of foreign states. Never before has South America seen a leader as determined as Bolivar, a man willing to sacrifice his life for the rights and freedom of the people by any means necessary. He was an excellent horseback rider, a man who killed a monk with his sword, an excellent strategist in the battleground, a general who enlisted the help of cannibals in his army, a man who escaped several assassination attempts, and a boy who played badminton with a young Spanish prince Ferdinand in his palace. They fit the description of Simon Bolivar; a man who accomplished more during his forty-seven years of lifetime, than forty seven men could hope to achieve in a hundred years. The Latin American Wars of Independence do not form an easy to tell narrative; there were different levels of violence, different revolutionary ideals and levels of popular participation throughout the Spanish colonies. Simon Bolivar was a man of integrity living among corruption, whose ideals and philosophies were seldom appreciated before his death, but they continue to be a basis of influence in modern South American society. The young and relentless general, Simon Jose Antonio de la Santisima Trinidad Bolivar became publicly known as the Liberator when he rid the South American colonies of three hundred years of Spanish rule. He was born into an aristocratic family on Caracas, Venezuela in 1783. During his early life, he was taught the non-conformists ways of Jean Jacques...

Monday, November 4, 2019

Facts that make a class productive and enjoyable Essay

Facts that make a class productive and enjoyable - Essay Example In the process, clear distinction will be brought forth between being productive and being occupied. The first step that needs to be observed by teachers is; teaching the right things. It is not accurate to assume that all the things teachers teach are usually relevant and of ‘good practice’. Most teachers have adopted the method of â€Å"mark to the objective†. This method may also be referred to as marking, quality or focused. Such method of teaching disregard objectives of learning. Most teaching methods have been preoccupied with predetermination of what would be called as core subjects to train children on. The focus is much laid on the national curriculum than the actual things from which the students will benefit. One way of dealing with this is to try to use practical things in class especially when illustrating some products. This should go hand in hand with the identification of the right objective and subsequently, teaching these objectives at the right time at appropriate level. Rather than judging the teachers on whether they met the objectives of t he teaching, focus should be on whether those teachers got the objectives right in the first place. Another significant step that the teacher should observe and is a great factor is; getting the students do the work by themselves. There should be a very clear balance between the time students are putting in the work and what the teachers put. Study conducted by Smith, et.al (pg 13) reveals that schools where teachers and student do the work at the ration of 20:80 per cent, performed better than otherwise. This also depended on the teaching of the right objectives at the right time. Introducing the students into actual practice enables them to be more productive and they tend to find learning interesting as well. Another very important stage of making learning productive and fun is; the organizing

Friday, November 1, 2019

What makes religion different from a cult Assignment

What makes religion different from a cult - Assignment Example In general, the main difference between them is that cult can be seen as an extremely closed ideological system based on strict worshiping of a leader. In contrast to the cult, religion can be viewed as a set of internal and external manifestations of human faith. In other words, any religion focuses on the internal search of the self in harmony with God or the Absolute. As is it known, any religion recognizes the value and importance of human desire to know one’s â€Å"I.† Religion can be viewed as a way for self-knowledge by referring to God or to the Absolute. Regardless of the type of religion, a believer should learn to control his/her â€Å"I.† In turn, this is possible as a result of learning the features of one’s soul, mind and psyche. Believers should open the way to their inner world, and religion is the way by which this can be done. Thus, religion is impossible without self-knowledge and the desire to understand the essence of one’s soul and nature. In fact, religion calls â€Å"to confront reality, to master the self† (Galvan). In this regard, religion cannot be identified with the cult. The cult should be viewed as a certain ritual practice, which does not aim at self-knowledge. In reality, the cult is a closed system, where the main role belongs to the leader. The task of its followers is to w orship the cult leader and glorify him. As a result, this understanding does not involve the pursuit of self-analysis and the search for one’s â€Å"I.† Any cult is based on a strict set of rules, where conformity and control play a particularly important role. As an exclusive system designed for a narrow circle of followers, the cult forbids any questions or doubts about its ideological base or leader. A person has the ability to become part of a certain cult only if he/she recognizes the ideas and beliefs underlying the cult. Moreover, religion cannot be considered as a cult for the simple reason that the concept of cult often â€Å"carries a

Wednesday, October 30, 2019

International Aspects Of Business Law Coursework - 1

International Aspects Of Business Law - Coursework Example One of the event was several boxes were dropped by the crane during loading of the consignment. It occurred due to overloading of the net through which the boxes were lifted. Secondly, the carrier during the course of voyage also encountered rough weather conditions. Now the matter of concern for the buyer namely, Nee Soon Wat was the extent of damage of materials in the dropped boxes. But after inspection of the dropped boxes he found that the objects were intact. So he formally accepted the goods and paid Sefton Toys for the consignment. But at the time of unloading of the consignment it was discovered that rest of the uninspected shipment got affected largely due to shifting during the rough weather of the voyage. The improperly stowed cargo was the reason for shifting of the boxes. Furthermore, some serious mistake in the date of the paper works related to bill of lading is also present. Some information regarding the shipping terms are also provided in this case study to resolve this problem. Those are: firstly, during this transaction shipping terms were under Incoterms 2000. Secondly, the contract made by them expressed to be subject to the UN Convention on Sales 1980 (Vienna Convention). Findings from the statements of law The contract between Sefton Toy’s and Nee Soon Wat was based on two contractual laws; Incoterms 2000 and UN Convention on Contracts for the International Sale of Goods. According to, UN Convention on Contracts for the International Sale of Goods the obligations of buyers and sellers are given below which will help to resolve this case. Obligations of the seller According to this Convention generally the obligations from seller’s end is the delivery of goods along with documents in conformity with the contract. This Convention also made supplementary rules which can be used in absence of agreement of contract. These rules states how, when and where the obligations should be performed by the sellers. It also provides numer ous rules about the seller’s obligations regarding quality of the commodities being sold. It suggests the seller must convey the commodities matching to the quality, quantity and description which are requisites of the buyer defined in the contract. The goods to be also packaged and marked according to the requisites of the buyer described in the contract. One significant rule which involve seller’s obligation is that the delivered merchandise should be free from third party rights or claims. There is another rule which is connected with the buyer’s obligation that is to inspect the goods. If any lack of conformity is discovered by the buyer in accord to the contract he must serve a notice within a rational period. It must be within 2 years from the delivery date of the consignment. (United Nations Convention on Contracts for the International, p.38) Obligations of the buyer According to this convention the obligations from the buyer’s end are making the payment for the goods and accepting the delivery in accordance to the contract. During making payment it also includes performance of duties

Monday, October 28, 2019

Representation of Women in History Essay Example for Free

Representation of Women in History Essay Throughout American history, women have been the backbone of the country, working at taking care of their families, and the country itself. The recognition of this is shown by the different representations of America in a female context. Whether as a insolent young Native American princess who has wronged her British mother, or as Roman goddess Columbia in her long, flowing white robes.   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   The major change in the way America was represented pictorially was brought about by Phillis Wheatley in 1775, when she sent her poem to George Washington describing America as a goddess called Columbia. The people at the time were quick to identify with this new interpretation as they wanted to distance themselves from the negative British representations of America as a Native American woman who was young and disobeying of her parental figure. Also at that time, colonists were thinking of America as a place of self-knowledge and exploration, creating libraries and other places of study, complete with mock Roman architecture that enforced the feeling of the â€Å"new Rome,† and they liked the fact that Columbia was shown as a Roman goddess of sorts.   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   When looking at the differences in the print by Edward Savage and the print dated 1866, there can be seen a change from Savages peaceful looking goddess Columbia, and then the armed fighting women that are in the 1866 picture. The earlier picture dated as 1796 shows Liberty wearing a wreath of flowers around her, offering a cup to an eagle and surrounded by billowing clouds and showing her upfront, away from any violence. The latter drawing from 1866 shows three women, two holding the flag pole, and one with a sword still fighting, surrounded by people. This picture comes at the end of the Revolution era, and depicts Americas fighting spirit which has emerged from the battle.   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   When looking at the example of the Eighteenth century book, Charlotte Temple by Susanna Rowson, the influence of the Columbian ideal can be shown by the book being of the seduction genre, which was very popular in that era. This type of story touched many in the nation, as people related their worrying about how they stood after going against Britain to the seduction of a young female who was brought the new land, and then tricked into getting pregnant, only to be left to die on her own. Many wondered would America suffer that same fate as the seduced young woman, or would the country triumph as the new goddess, Columbia. It is no surprise that during such a perilous time in history that people were drawn to these seduction genre stories to the point of believing in their hearts that Rowsons work was non-fiction, which is wasnt.   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   The recent 2005 portrait of Sacajawea is a new drawing on a golden dollar coin. She is shown as looking back, her hair drawn back, and having her son, Jean Baptiste strapped to her. This representation of her is striking with her large, dark eyes, and her true Native American features which are very pronounced and stunning. In earlier representations of Native American women, the facial features are all very close to what the features of drawings of white women at the time. These earlier images were closer to the facial likeness of early pictures of Columbia.   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   The United States mint clearly made this coin to represent the anniversary of the Lewis and Clark expedition, dated 1804. The recent golden dollar was dated 2005, which means that it was conceived of and based on a 2004 date, exactly 200 years apart. The coin is also meant to commemorate the Native American people themselves in history.   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   The representation of Columbia in American history can be seen as the evolution of the country itself. As society grew, and the perception of what it meant to be an American changed, the figures of women changed with it. The spirit of Columbia is equated with the spirit of our nation, and the artistry used to show that spirit in female form is still being used today, represented by the Sacajawea coin, celebrating the community ideal of what is is to be American.

Saturday, October 26, 2019

the consequences of sin :: essays research papers fc

The Consequences of Sin â€Å"The theme of the stories has been variously stated as the reality of sin, the occurrence of evil, the secret sin and hypocrisy of all persons, the hypocrisy of Puritanism, the results of doubt or disbelief, the devastating effects of moral skepticism, or the demoralizing effects of the discovery that all men are sinners and hypocrites† (McKeithan 93). Although â€Å"The Minister’s Black Veil† and â€Å"Young Goodman Brown† both deal with the obsession with sin, Nathaniel Hawthorne illuminates the different consequences. First of all there are many similarities in â€Å"The Minister’s Black Veil† and â€Å"Young Goodman Brown†. One of the many similarities is that both towns seem to be corrupt with sin. Mr. Hooper knows that everyone is not perfect in his town. Although it very well shows in the end of the story when Mr. Hooper expresses himself, â€Å"I look around me, and, lo! On every visage a Black Veil (Minister 882).† Young Goodman Brown knows that he has been raised by Puritan ideals yet he sees his mentors going against everything he has taught him. Goodman Brown’s account of when he was at the witch meeting was, â€Å"The fiend worshippers were seen; the smile of welcome gleamed darkly on every visage (Young 1040).† Both Mr. Hooper and Brown also have the same ideals. They both believe in Puritan ideas and beliefs but they both have some kind of conflict with sin. â€Å"For the hardened Puritan, his humanity was sinful enough, end he wore it the way a medieval penitent would his hair shirt. Anything less than absolute perfection was absolute corruption (Morsberger 456).† Another relation that Hooper and Brown comprise of is that they both lose the girl they adore in the short stories. Hooper loses his girl, Elizabeth by not taking off the veil that everyone in town is talking about. Brown on the other hand loses his girl, Faith from the very beginning when he left her at their home. The differences in â€Å"The Minister’s Black Veil† and â€Å"Young Goodman Brown† are numerous as well as their similarities. One of the differences is how both characters dealt with sin. Reverend Hooper tries to deal with the sin that he may have committed by wearing a black veil that covers his face till the day he dies. â€Å"If I hide my face for sorrow, there is cause enough†¦ and if I cover it for secret sin, what mortal might not do the same (Minister 878).

Thursday, October 24, 2019

paintball :: essays research papers

Paintball Misrepresented Sport When you here about paintball in the news, it's always a story of someone losing an eye or committing a crime. Is this what paintball is about? Definitely not! Lets first start off by saying, that accusing the sport of paintball, for criminals vandalizing property with paintball markers (They are actually classified as markers, not guns, because they mark people, like in a game of tag), is like blaming the sport of baseball, for people that fight or injure people with bats. It's like accusing football for encouraging people to fight. Of course though, football is never blamed for that. Some people also would like to say that paintball is too dangerous, and people get injured way too often because it's unsafe to play. The fact is, those people couldn't be more wrong. Paintball requires a mask to be worn on all public fields. Neck protectors and vests are also optional if you feel like it. Most people would probably be surprised to learn that players and referees take extra care to make sure that all the players are safe in a game. National averages even show that paintball has a lower injury rate than bowling and golf! So how did those kids in the news loose an eye? Simple, they didn't wear the right protection and were probably playing on their own field, without refs and proper marker testing. Playing paintball without masks is the equivalent of playing tackle football with pads and helmets, which means someone could get hurt. Is football ever criticized for severe injuries? Almost never. So why should paintball be any different? So, before you decide to criticize paintball, first go to you local field (here in Utah, you can go to Paintball Planet or Army Navy Surplus) and try a game. Then create your opinion. Most people who go actually find it very fun. It gets your adrenaline pumping and has a frantic (but fun) feel to it. It also has some value. Playing the game a lot develops excellent hand-eye-coordination, teaches teamwork, trust, and careful planning.

Wednesday, October 23, 2019

Microeconomics and the Law of Supply and Demand Essay

During the simulation of Goodlife Inc. I was able to see how the effects of a lower rent verses a higher rent had on the vacancy percentage. In our simulation the town of Atlantis had only one rental agency with apartments available. There were single family homes available too but the need for renting was with apartments. I got to see how the supply and demand worked with this rental property simulation. The town of Atlantis saw a rise in population which led to a higher demand for vacant units. This caused Goodlife to raise its rent to meet the growing demand for its available units. But as the demand for renting the units fell so did the demand. This meant Goodlife had to lower its rental price to meet the lesser demand for renting. This is a good example of microeconomics. When I looked at the simulation for examples of macroeconomics I found it when the government stepped in to put a cap on the rent amount. In the simulation there was a survey that showed individuals were living outside of Atlantis rather than renting a place in the city limits where they work. As many of us do currently in our own lives we usually can’t afford to live in the city or area where the best jobs are. I am a prime example, I commute 50 miles one way to work as it’s where the best salary is. I live in an area where housing and rents are affordable and the overall cost of living is cheaper too. In the simulation, the government put a cap of $1550 for the monthly rent of a two bedroom apartment. This was meant to allow middle class families and individuals the opportunity to live where they work. Because of the rent cap, Goodlife didn’t rent out every apartment available as profits would not be able to keep up with the maintenance cost of having every uni t rented. When we look at what a shift in supply and demand curve we see that clearly when Lintech Inc. moved into Atlantis creating more jobs. As soon as  Lintech did this it increased the population of Atlantis which was the shift in the supply curve. This was a negative impact for Goodlife as there was more population needing apartments and not enough two bedroom apartments available. The demand curve now goes up because of the population growth and need for more apartments. With Lintech moving into the city and the population now increasing the demand it means that the quantity demand is now more than quantity supplied at the original equilibrium. This also caused a temporary shortage in the market of two bedrooms apartments in Atlantis. Rental rates went up due to the higher demand. Also quantity demand decreased and quantity supplied increases which leads to a reduction of apartments or shortage of apartments. To get to the new equilibrium the adjustment needs to get between the new demand curve and the original supply curve. When the new equilibrium is reached the rental rates are now higher than they were before. This also means that the number of apartments that are demanded and the supply of apartments has also increased. I can apply this supply and demand to my workplace job. When I have a customer that wants to ship more packages with us on a new daily bases I have to look at the new demand. Before their demand for shipping more I didn’t need extra couriers and trucks to handle the day’s deliveries. Now with the new demand I have to get my supply of couriers and trucks at the last minute. This causes me to have to spend more money to rent more vans and hire more employees. Overall my cost go up with the demand of more shipping packages, but so does my profit as I am able to use more supplies to handle the new demand. To better understand how the concept of microeconomics helps me understand the factors that affect shifts in supply and demand on the equilibrium price and quantity I have to look at the competitors and their prices. The bidding for the competition and where it comes across the equilibrium is the point at which the new equilibrium is now. But under the view of macroeconomics it is seen when the jobs and population grew. This effected the increase and decrease on the available apartments. Now the equilibrium  for rentals is higher then it was before the move in by Lintech. So is the number of apartments demanded and supplies has increased. In the simulation we saw how with lower prices meant that the demand was higher. But with the demand for apartments came higher prices. But if the price was to increase too much the demand for apartments would decrease. There is also a possibility that it could remain the same over a short period of time, then decrease if prices didn’t change. This simulation showed lots of possibilities that could exists in today’s world, or at least in Atlantis. We see what price could do to supply and demand for apartments and what demand could do to price and supply. When either is moved or switched leads to various outcomes the will lead an economy like Atlantis to either run out of its supply of apartments or have an increase in supply of apartments because the prices are too high. Reference Microeconomics, Ninth Edition, David C. Colander (2013) University of Phoenix

Tuesday, October 22, 2019

predictors of husband to wife violence essays

predictors of husband to wife violence essays Critical Analysis of Journal Article Article: Feldbau-Khon, S., Heyman, R., and OLeary, K. (1998). Major depressive disorder and depressive symptomatology as predictors of husband to wife physical abuse. Violence and Victims, 13, 347-359. The work of Feldbau-Khon, S., Heyman, R., and OLeary, K. is described in the article, Major Depressive Disorder and Depressive Symptomatology as Predictors of Husband to Wife Physical Aggression. The authors tested the link between a husbands depressive symptomatology and the frequency of physical aggression toward his wife. Also tested was the husbands Major Depressive Disorder and the frequency of physical aggression towards his wife. The authors had four hypotheses. 1: Clinically depressed men are more physically aggressive. 2: Depressive symptomatology is associated with frequency of physical aggression. 3: Depressive symptomatology effects on physical aggression are accounted for by other variables. 4: Depressive symptomatology effects on psychological aggression are accounted for by other variables. The study assessed physically aggressive men who volunteered for treatment with their wives. Participants responded to newspaper announcements offering free therapy for relationship conflicts. All spouses completed three-hour assessments consisting of structured interviews and self-report measures. Almost one third had moderate levels of depressive symptomatology, but only 11% met the criteria for Major Depressive Disorder (MDD). Although a significant relationship between increased depressive symptomatology and frequency of physical aggression was found, the relationship was most likely accounted for by self- reported anger. One weakness with this study is the makeup of the sample. The racial composition of the sample was 1.3% Black, 1.3% Asian, and 97% White. No Hispanics were included in the study altho ...

Monday, October 21, 2019

US Drug Policy essays

US Drug Policy essays Q. Would the Amsterdam model be a useful government response to hallucinogen and marijuana use in this country? Why or why not? Amsterdams coffee shops and cafes are notorious for the tolerated exchange of hashish and marijuana. This example goes completely against the moral principles underlying the United States drug policy. The United States drug policy stands by the zero tolerance rules. Our drug culture does not believe in any such thing as a use of an illegal drug, only abuse. So, why arent the Dutch facing as many drug related problems as we are? Is a more laissez-faire approach to drugs the answer? We arent winning the war on drugs. It is clear that the illegal drug use and drug related problems have increased in the United States. I think that the Amsterdam model may act a useful government response to hallucinogen and marijuana use in the United States. We have tried everything from stricter punishments to spending more dollars on drug prevention programs. The anti-drug law has led to the criminalization of more drugs and the imprisonment of more drug users. The cost of prohibition of drugs is getting pricier every year. Lester Grinspoon and James Bakalar stated, The arrest of more than 300,000 people a year on marijuana charges contributes the clogging of courts and the overcrowding of prisons. Federal, state, and local governments now spend nearly ten billion dollars a year on drug enforcement and hundreds of millions more to house and feed drug dealers and users in local, state and federal prisons(80). The drug related problems are increasing rather than decreasing . Isnt it time that we searched for a better alternative to fighting the war on drugs. I am not saying that legalizing all drugs is the solution. I definitely dont believe that legalizing all drugs would work in our society. I dont think that our society is mature enough to handle the responsib...